Spin Dynamics in Monochalcogenides

The ability to dynamically control spin with polarized light offers opportunities for fast, nondestructive, and magnet free control over spin information. Manipulating spin with light has been achieved in III-V and II-VI semiconductors through spin polarized optical selection rules that occur due to strong atomic spin-orbit coupling in these systems [1]. Although these traditional systems have pioneered the field of optical spin-based devices, there are other novel platforms for optical spin control.

The emergence of two-dimensional van der Waals materials offers an alternative low-dimensional platform for spintronic phenomena. Indium selenide (InSe), a group-III monochalcogenide van der Waals material, has shown promise for optoelectronics due to its high electron mobility, tunable direct band gap, and quantum transport [2,3]. In addition to these properties, InSe has also been proven to have spin-polarized optical selection rules similar to that of III-V and II-VI semiconductors, allowing optical orientation of spin [4].Optical orientation of spin is an important prerequisite for optospintronic phenomena and devices, and these first demonstrations of layer-dependent optical excitation of spins in InSe lay the foundation for combining layer-dependent spin properties with advantageous electronic properties found in this material.

[1] I. Zutic, J. Fabian, and S. Das Sarma, “Spintronics: Fundamentals and applications,” Rev. Mod. Phys., vol. 76, pp. 323–410, 2 (2004).

[2] K. Premasiri and X. P. Gao, “Tuning spin-orbit coupling in 2D materials for spintronics: A topical review,” Journal of Physics Condensed Matter, vol. 31, no. 19 (2019)

[3] D. A. Bandurin, A. V. Tyurnina, G. L. Yu, et al., “High electron mobility, quantum Hall effect and anomalous optical response in atomically thin InSe,” Nature Nanotechnology, vol. 12, no. 3, pp. 223–227 (2017)

[4] J. Nelson, T. K. Stanev, D. Lebedev, et al., “Layer-dependent optically induced spin polarization in InSe,” Phys. Rev. B, vol. 107, p. 115 304, 11 (2023).